DEVELOPMENT OF HIGH SPEED RRLC METHOD FOR QUANTITATIVE DETERMINATION OF SOME PESTICIDE RESIDUES IN APPLE JUICE
Article Sidebar
Published:
Mar 1, 2016
Keywords:
direct determination, methidathion, propiconazole, high speed RRLC, apple juice
Main Article Content
Abstract
Possibilities of normal-phase (NP) and reversed-phase (RP) liquid chromatography methods for determination of methomyl, methidathion and propiconazole residues in apple juice were studied. The investigations were carried out on various analytical columns using RRLC (Rapid Resolution Liquid Chromatography) system coupled with UV-Vis diode array detector. The best conditions for separation and quantitative determination of tested pesticides were obtained using reversed-phase mode and Purospher® Star RP-18 endcapped (30 mm × 4 mm; 3 μm) column. Fast and simple method for direct determination of methidathion and propiconazole in different apple juice matrix was developed. In accordance to European Commission regulation the tested parameters for method validation (selectivity, linearity, precision, limit of detection, limit of quantification and accuracy) were satisfied.
Downloads
Download data is not yet available.
Article Details
Section
Articles
References
Blasco, C., Font G., Picó, Y., (2008). Solid-phase microextraction-liquid chromatography-mass spectrometry applied to the analysis of insecticides in honey, Food Additives & Contaminants: Part A, Vol. 25, No. 1, pp. 59-69.
Boulaid, M., Aguilera, A., Busonera, V., Camacho, F., Monterreal, A. V., Valverde, A., (2007). Assessing supercritical fluid extraction for the analysis of fipronil, kresoxim-methyl, acrinathrin, and pyridabenresidues in melon. J Environ Sci Health B., Vol. 42, No. 7, pp. 809-815.
del Castillo, M. L., Rodriguez-Valenciano, M., de la Peña, Moreno, F., Blanch, G. P., (2012). Evaluation of pesticide residue contents in fruit juice by solid-phase microextraction and multidimensional gas chromatography coupled with mass spectrometry. Talanta, Vol. 30, No. 89, pp. 77-83.
Fernandes, V. C., Domingues, V. F., Mateus, N., Delerue-Matos, C., (2011). Determination of Pesticides in Fruit and Fruit Juices by Chromatographic Methods. An Overview, Journal of Chromatographic Science, Vol. 49, pp. 715-730.
Guangdong, X., Daming, D., Tongqing, L., Yang L., Ling Z., Dongyan Z., Chunjiang Z., (2015). Detection of Pesticide (Chlorpyrifos) Residues on Fruit Peels Through Spectra of Volatiles by FTIR, Food Analytical Methods, May, Vol. 8, No. 5, pp. 1341-1346
Hernández, F., Cervera, M. I., Portolés, T., Beltrán, J., Pitarch E., (2013). The role of GC-MS/MS with triple quadrupole in pesticide residue analysis in food and the environment, Anal. Methods, Vol. 5, pp. 5875-5894.
Guidance document on analytical quality control and validation procedures for pesticide residues analysis in food and feed. SANCO/12571/ 2013 pp. 20-26.
Jamshidi, B., Mohajerani, E., Jamshidi, J., Minaei, S., Sharifi, A., (2015). Non-destructive detection of pesticide residues in cucumber using visible/near-infrared spectroscopy, Food Additives & Contaminants: Part A, Vol. 32, No. 6, pp. 857-863.
Jokanović, M., (2012). The Impact of Pesticides Published First Edition by Academy Publish. org, USA pp.19.
Liu, H., Kong, W., Gong, B., Miao, Q., Qi, Y., Yang, M., (2015). Rapid analysis of multi-pesticides in Morinda officinalis by GC-ECD with accelerated solvent extraction assisted matrix solid phase dispersion and positive confirmation by GC-MS. J Chromatogr B Analyt Technol Biomed Life Sci., Vol. 1, No. 974, pp. 65-74.
Martínez-Domínguez, G., Nieto-García, A. J., Romero-González, R., Garrido Frenich, A., (2015). Application of QuEChERS based method for the determination of pesticides in nutraceutical products (Camellia sinensis) by liquid chromatography coupled to triple quadrupole tandem mass spectrometry, Food Chemistry, Vol. 177, No. 15, pp. 182–190.
Moreno-González, D., Huertas-Pérez, F. J., Gámiz-Gracia, L., García-Campañ, A. M., (2015). High-Throughput Methodology for the Determination of 33 Carbamates in Herbal Products by UHPLC–MS/MS, Food Analytical Methods, Vol. 8, No. 8, pp. 2059-2068.
Moura1, P., Alexandre, C., Geraldo, A., Botton M., (2012). Residual effect of pesticides used in integrated apple production on chrysoperlaexterna (hagen) (neuroptera: chrysopidae) larvae, chilean journal of agricultural research 72(2) april-june, http://www.scielo.cl/scielo.php?script=sci_arttext&pid = S0718-58392012000200009.
Nollet, Leo M. L., 2004, Handbook of Food Analysis: Residues and other food component analysis, Marcel Dekker, Inc, New York, USA, pp. 1187
Páleníková, A., Martínez-Domínguez, G., Javier Arrebola, F., Romero-González, R., Hrouzková, S., Garrido Frenich, A., (2015). Occurrence of pesticide residues and transformation products in different types of dietary supplements, Food Additives & Contaminants: Part A, Vol. 32, No. 6, pp. 849-856.
Pesticide Residues in Foods by Acetonitrile Extraction and Partitioning with Magnesium Sulfate Gas Chromatography/Mass Spectrometry and Liquid Chromatography/Tandem Mass Spectrometry, AOAC Official Method 2007.01, p://www.weber.hu/PDFs/QuEChERS/AOAC_2007_01.pdf
Rosenblum, L., Hieber, T., Morgan, J., (2001). Determination of pesticides in composite dietary samples by gas chromatography/mass spectrometry in the selected ion monitoring mode by using a temperature-programmable large volume injector with preseparation column. J AOAC Int., Vol. 84, No. 3 pp. 891-900.
Słowik-Borowiec, M., (2015). Validation of a QuEChERS-Based Gas Chromatographic Method for Multiresidue Pesticide Analysis in Fresh Peppermint Including Studies of Matrix Effects, Food Analytical Methods, Vol. 8, No. 6, pp. 1413-1424.
Takatori, S., Okihashi, M., Kitagawa, Y., Fukui, N., Kakimoto, O., Obana, H., (2011). Rapid and Easy Multiresidue Method for Determination of Pesticide Residues in Foods Using Gas or Liquid Chromatography–Tandem Mass Spectrometry, Pesticides - Strategies for Pesticides Analysis, chapter 8, 197-214, Edited by Prof. Margarita Stoytcheva Publisher: InTech http://www.intechopen.com/books/pesticides-strategies-for-pesticides-analysis/rapid-and-easy-multiresidue-method-for-determination-of-pesticide-residues-in-foods-using-gas-or-liq
Tuzimski, T., Rejczak, T., (2016). Application of HPLC–DAD after SPE/QuEChERS with ZrO2-based sorbent in d-SPE clean-up step for pesticide analysis in edible oils, Food Chemistry, Vol. 190, pp. 71–79.
Wang J., Chow W., Leung D., (2011). Applications of LC/ESI-MS/MS and UHPLC/Qq-TOF-MS for the determination of 141 pesticides in tea, J AOAC Int., Vol. 94, No. 6, pp. 1685-714.
Wenbi, G., Zhen, L., Jiangyu, L., Yifan, H., Yongqiang, M., Hongyan, Z., (2015). Unique Graphitic Carbon Nitride Nanovessels as Recyclable Adsorbent for Solid Phase Extraction of Benzoylurea Pesticides in Juices Samples, Food Analytical Methods, Vol. 8, No. 9, pp. 2202-2210.
Xiaoli, C., Suhua, L., Xiaoqian, Y., Zhong, L., Lanzheng, L., (2015). A Modified QuEChERS Sample Preparation Method for Simultaneous Determination of 62 Pesticide Residues in Edible Fungi Using Gas Chromatography–Triple Quadrupole Mass Spectrometry, Food Analytical Methods, Vol. 14, pp 1-12
Zhao, L., Shultz, D., Stevens, J., (2012). Analysis of pesticide residues in apple using Agilent bond elut QuEChERS AOAC kits by GC/MS, Agilent technologies, pp. 1-13, https://www.agilent.com/cs/library/applications/5990-4068EN.pdf
Zhou, M., Hu, N., Shu, S., Wang, M., (2015). Molecularly Imprinted Nanomicrospheres as Matrix Solid-Phase Dispersant Combined with Gas Chromatography for Determination of Four Phosphorothioate Pesticides in Carrot and Yacon J Anal Methods Chem., Published online, http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4411505/
Boulaid, M., Aguilera, A., Busonera, V., Camacho, F., Monterreal, A. V., Valverde, A., (2007). Assessing supercritical fluid extraction for the analysis of fipronil, kresoxim-methyl, acrinathrin, and pyridabenresidues in melon. J Environ Sci Health B., Vol. 42, No. 7, pp. 809-815.
del Castillo, M. L., Rodriguez-Valenciano, M., de la Peña, Moreno, F., Blanch, G. P., (2012). Evaluation of pesticide residue contents in fruit juice by solid-phase microextraction and multidimensional gas chromatography coupled with mass spectrometry. Talanta, Vol. 30, No. 89, pp. 77-83.
Fernandes, V. C., Domingues, V. F., Mateus, N., Delerue-Matos, C., (2011). Determination of Pesticides in Fruit and Fruit Juices by Chromatographic Methods. An Overview, Journal of Chromatographic Science, Vol. 49, pp. 715-730.
Guangdong, X., Daming, D., Tongqing, L., Yang L., Ling Z., Dongyan Z., Chunjiang Z., (2015). Detection of Pesticide (Chlorpyrifos) Residues on Fruit Peels Through Spectra of Volatiles by FTIR, Food Analytical Methods, May, Vol. 8, No. 5, pp. 1341-1346
Hernández, F., Cervera, M. I., Portolés, T., Beltrán, J., Pitarch E., (2013). The role of GC-MS/MS with triple quadrupole in pesticide residue analysis in food and the environment, Anal. Methods, Vol. 5, pp. 5875-5894.
Guidance document on analytical quality control and validation procedures for pesticide residues analysis in food and feed. SANCO/12571/ 2013 pp. 20-26.
Jamshidi, B., Mohajerani, E., Jamshidi, J., Minaei, S., Sharifi, A., (2015). Non-destructive detection of pesticide residues in cucumber using visible/near-infrared spectroscopy, Food Additives & Contaminants: Part A, Vol. 32, No. 6, pp. 857-863.
Jokanović, M., (2012). The Impact of Pesticides Published First Edition by Academy Publish. org, USA pp.19.
Liu, H., Kong, W., Gong, B., Miao, Q., Qi, Y., Yang, M., (2015). Rapid analysis of multi-pesticides in Morinda officinalis by GC-ECD with accelerated solvent extraction assisted matrix solid phase dispersion and positive confirmation by GC-MS. J Chromatogr B Analyt Technol Biomed Life Sci., Vol. 1, No. 974, pp. 65-74.
Martínez-Domínguez, G., Nieto-García, A. J., Romero-González, R., Garrido Frenich, A., (2015). Application of QuEChERS based method for the determination of pesticides in nutraceutical products (Camellia sinensis) by liquid chromatography coupled to triple quadrupole tandem mass spectrometry, Food Chemistry, Vol. 177, No. 15, pp. 182–190.
Moreno-González, D., Huertas-Pérez, F. J., Gámiz-Gracia, L., García-Campañ, A. M., (2015). High-Throughput Methodology for the Determination of 33 Carbamates in Herbal Products by UHPLC–MS/MS, Food Analytical Methods, Vol. 8, No. 8, pp. 2059-2068.
Moura1, P., Alexandre, C., Geraldo, A., Botton M., (2012). Residual effect of pesticides used in integrated apple production on chrysoperlaexterna (hagen) (neuroptera: chrysopidae) larvae, chilean journal of agricultural research 72(2) april-june, http://www.scielo.cl/scielo.php?script=sci_arttext&pid = S0718-58392012000200009.
Nollet, Leo M. L., 2004, Handbook of Food Analysis: Residues and other food component analysis, Marcel Dekker, Inc, New York, USA, pp. 1187
Páleníková, A., Martínez-Domínguez, G., Javier Arrebola, F., Romero-González, R., Hrouzková, S., Garrido Frenich, A., (2015). Occurrence of pesticide residues and transformation products in different types of dietary supplements, Food Additives & Contaminants: Part A, Vol. 32, No. 6, pp. 849-856.
Pesticide Residues in Foods by Acetonitrile Extraction and Partitioning with Magnesium Sulfate Gas Chromatography/Mass Spectrometry and Liquid Chromatography/Tandem Mass Spectrometry, AOAC Official Method 2007.01, p://www.weber.hu/PDFs/QuEChERS/AOAC_2007_01.pdf
Rosenblum, L., Hieber, T., Morgan, J., (2001). Determination of pesticides in composite dietary samples by gas chromatography/mass spectrometry in the selected ion monitoring mode by using a temperature-programmable large volume injector with preseparation column. J AOAC Int., Vol. 84, No. 3 pp. 891-900.
Słowik-Borowiec, M., (2015). Validation of a QuEChERS-Based Gas Chromatographic Method for Multiresidue Pesticide Analysis in Fresh Peppermint Including Studies of Matrix Effects, Food Analytical Methods, Vol. 8, No. 6, pp. 1413-1424.
Takatori, S., Okihashi, M., Kitagawa, Y., Fukui, N., Kakimoto, O., Obana, H., (2011). Rapid and Easy Multiresidue Method for Determination of Pesticide Residues in Foods Using Gas or Liquid Chromatography–Tandem Mass Spectrometry, Pesticides - Strategies for Pesticides Analysis, chapter 8, 197-214, Edited by Prof. Margarita Stoytcheva Publisher: InTech http://www.intechopen.com/books/pesticides-strategies-for-pesticides-analysis/rapid-and-easy-multiresidue-method-for-determination-of-pesticide-residues-in-foods-using-gas-or-liq
Tuzimski, T., Rejczak, T., (2016). Application of HPLC–DAD after SPE/QuEChERS with ZrO2-based sorbent in d-SPE clean-up step for pesticide analysis in edible oils, Food Chemistry, Vol. 190, pp. 71–79.
Wang J., Chow W., Leung D., (2011). Applications of LC/ESI-MS/MS and UHPLC/Qq-TOF-MS for the determination of 141 pesticides in tea, J AOAC Int., Vol. 94, No. 6, pp. 1685-714.
Wenbi, G., Zhen, L., Jiangyu, L., Yifan, H., Yongqiang, M., Hongyan, Z., (2015). Unique Graphitic Carbon Nitride Nanovessels as Recyclable Adsorbent for Solid Phase Extraction of Benzoylurea Pesticides in Juices Samples, Food Analytical Methods, Vol. 8, No. 9, pp. 2202-2210.
Xiaoli, C., Suhua, L., Xiaoqian, Y., Zhong, L., Lanzheng, L., (2015). A Modified QuEChERS Sample Preparation Method for Simultaneous Determination of 62 Pesticide Residues in Edible Fungi Using Gas Chromatography–Triple Quadrupole Mass Spectrometry, Food Analytical Methods, Vol. 14, pp 1-12
Zhao, L., Shultz, D., Stevens, J., (2012). Analysis of pesticide residues in apple using Agilent bond elut QuEChERS AOAC kits by GC/MS, Agilent technologies, pp. 1-13, https://www.agilent.com/cs/library/applications/5990-4068EN.pdf
Zhou, M., Hu, N., Shu, S., Wang, M., (2015). Molecularly Imprinted Nanomicrospheres as Matrix Solid-Phase Dispersant Combined with Gas Chromatography for Determination of Four Phosphorothioate Pesticides in Carrot and Yacon J Anal Methods Chem., Published online, http://www.ncbi.nlm.nih.gov/pmc/articles/PMC4411505/